{"product_id":"9783527354634","title":"Radical Brook Rearrangement","description":"\u003ch1\u003eRadical Brook Rearrangement\u003c\/h1\u003e\u003ch3\u003eXiao Shen | Yunxiao Zhang | Gang Zhou\u003c\/h3\u003e\u003cdiv\u003e\u003cb\u003eScience \/ Chemistry \/ Physical \u0026amp; Theoretical\u003c\/b\u003e\u003c\/div\u003e\u003cbr\u003e\u003cdiv\u003e\n\u003cp\u003e\u003cb\u003eIn-depth monograph presenting innovative radical methodologies in the Brook rearrangement and their utility in organic synthesis\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003ci\u003eRadical Brook Rearrangement\u003c\/i\u003e chronicles the evolution of radical Brook rearrangements, synthesizes recent advances in the field, and outlines future research directions. The book focuses on three key reactive intermediates — α-siloxy radicals, siloxycarbenes, and silenes — providing detailed analyses of their generation methods, substrate scope, mechanistic insights, and synthetic applications, along with practical experimental protocols.\u003c\/p\u003e \u003cp\u003eReaders will find insights on alkoxy radical generation, photocatalytic systems, and the selection of radical\/carbene acceptors. This book deliberately focuses on radical processes, excluding anionic pathways.\u003c\/p\u003e \u003cp\u003eWritten by a team of highly qualified researchers in the field, \u003ci\u003eRadical Brook Rearrangement \u003c\/i\u003eincludes information on:\u003c\/p\u003e \u003cul\u003e \u003cli\u003eGeneration of siloxycarbenes for metal siloxycarbene reaction, with information on aminooxycarbene reactions\u003c\/li\u003e \u003cli\u003eGeneration of siloxycarbenes for nucleophilic addition reaction, covering aldehydes and ketones as electrophiles and other electrophilic reagents\u003c\/li\u003e \u003cli\u003eGeneration of α-siloxy silyl radicals with (TMS)3SiOH, covering photoredox reactions and metallaphotoredox reactions with (TMS)3SiNHAd\u003c\/li\u003e \u003cli\u003eGeneration of α-siloxy radicals with α-silyl alcohol, covering metal-free, metal-catalyzed, photocatalyzed, and electrophotocatalyzed reactions\u003c\/li\u003e \u003c\/ul\u003e \u003cp\u003eContaining cutting-edge research discoveries on the subject, \u003ci\u003eRadical Brook Rearrangement\u003c\/i\u003e is an essential reference for chemists across specializations, materials scientists, and professionals in the pharmaceutical industry.\u003c\/p\u003e\n\u003c\/div\u003e\u003cdiv\u003e \u003cp\u003e\u003cb\u003eXiao Shen\u003c\/b\u003e is Professor at the Institute for Advanced Studies, Engineering Research Center of Organosilicon Compounds \u0026amp; Materials, Ministry of Education, State Key Laboratory of Metabolism and Regulation in Complex Organisms, Wuhan University, China. He is the winner of 2025 RSC Fluorine Prize. He serves on the Advisory Board of Chem Catalysis, the Early-Career Advisory Board of Organic Chemistry Frontiers, and is an Early-Career Editorial Board Member for Chinese Chemical Letters and the Chinese Journal of Organic Chemistry.\u003c\/p\u003e \u003cp\u003e\u003cb\u003eYunxiao Zhang\u003c\/b\u003e is a postdoctoral fellow of The Institute for Advanced Studies at Wuhan University, China.\u003c\/p\u003e \u003cp\u003e\u003cb\u003eGang Zhou\u003c\/b\u003e is a postdoctoral fellow of The Institute for Advanced Studies at Wuhan University, China.\u003c\/p\u003e\n\u003c\/div\u003e\u003cbr\u003e\u003ctable\u003e\n\u003ctr\u003e\n\u003ctd\u003ePublication Date: \u003c\/td\u003e\n\u003ctd\u003e11 May 2026\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd\u003ePublisher: \u003c\/td\u003e\n\u003ctd\u003eWiley\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd\u003eImprint: \u003c\/td\u003e\n\u003ctd\u003eWiley-VCH\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd\u003eISBN-13: \u003c\/td\u003e\n\u003ctd\u003e9783527354634\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd\u003eFormat: \u003c\/td\u003e\n\u003ctd\u003eHardback\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd\u003ePage Count: \u003c\/td\u003e\n\u003ctd\u003e336\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd\u003eWeight (oz): \u003c\/td\u003e\n\u003ctd\u003e24.0\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/table\u003e","brand":"Wiley","offers":[{"title":"Default Title","offer_id":44477087252620,"sku":"9783527354634","price":143.0,"currency_code":"USD","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0710\/9545\/1788\/files\/9783527354634.jpg?v=1780617215","url":"https:\/\/lateknightbooks.com\/products\/9783527354634","provider":"Late Knight Books and Services, LLC","version":"1.0","type":"link"}