This book constitutes the thoroughly refereed post-conference proceedings of the Second International ICST Conference on Personal Satellite Services, PSATS 2010, held in Rome, Italy, Februray 2010. The conference included a keynote speech, 4 regular technical tracks and 4 special sessions consisting of 33 high-quality scientific papers. These cover various topics such as Satellite Communications: Coding and Modulations, Multimedia Integration, Satellite Network: Quality of Service and Architectures and Applications and Services, as well as Delay-Tolerant Networks, Quantum Satellite Communications, Access Quality Processing and Applications of Satellite Imagery.