{"product_id":"9783642510267","title":"Reactivity and Structure: Concepts in Organic Chemistry","description":"\u003ch1\u003eReactivity and Structure: Concepts in Organic Chemistry\u003c\/h1\u003e \u003ch2\u003eOki, Michinori\u003c\/h2\u003e \u003cp\u003eRotation about the Carbon-Carbon single bond is generally\nregarded to be    unrestricted. About 50 years ago, rotational\nisomers were found to exhibit  optical activity: substituted\nbiphenyl derivatives. However, the author has investigated\nother classes of compounds that have stable                    rotational\nisomers at room temperature. These compounds can serve           as\nmodels for studying very weak intermolecular interactions,\nthat are  difficult to observe. Even diastereotopic groups\nshow different chemical    reactivity.\nFrom the contents: The \"Free Rotation Concept\" -                Rotamer\nPopulations - Barriers to Rotation - Reactivity of\nRotational   Isomers.\u003c\/p\u003e \u003ch3\u003eDetails\u003c\/h3\u003e \u003cp\u003ePublished by: Springer\u003c\/p\u003e \u003cp\u003ePublication Date: 2012-05-02\u003c\/p\u003e \u003cp\u003eFormat: Paperback\u003c\/p\u003e \u003cp\u003eISBN-13: 9783642510267\u003c\/p\u003e \u003cp\u003eDOI: 10.1007\/978-3-642-51024-3\u003c\/p\u003e \u003cp\u003eDimensions: 235cm x155cm\u003c\/p\u003e \u003cp\u003ePages: 172\u003c\/p\u003e ","brand":"Springer Berlin Heidelberg","offers":[{"title":"Default Title","offer_id":47672149377164,"sku":"9783642510267","price":49.49,"currency_code":"USD","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0710\/9545\/1788\/files\/9783642510267.jpg?v=1776520384","url":"https:\/\/lateknightbooks.com\/products\/9783642510267","provider":"Late Knight Books and Services, LLC","version":"1.0","type":"link"}