{"product_id":"9789811378300","title":"Chemistry of Thioamides","description":"\u003ch1\u003eChemistry of Thioamides\u003c\/h1\u003e \u003ch2\u003eMurai, Toshiaki\u003c\/h2\u003e \u003cp\u003e\u003c\/p\u003e\u003cdiv\u003e\n\u003cp\u003eThis book covers whole aspects of the sulfur isologues of amides. Starting from the synthetic methods of thioamides, a range of synthetic applications to the construction of carbon–sulfur and carbon–carbon bonds, to asymmetric reactions, to formation of heterocycles are described.\u003c\/p\u003e\n\n\u003cp\u003eAmong the array of thiocarbonyl compounds, thioamides are readily handled in room temperature air. Some of their characteristic features are that the polarity of C=S bonds in thioamides is much smaller than C=O bonds in ordinary amides, that thioamides possess higher HOMO and lower LUMO when compared with those of ordinary amides, and that carbon atoms alpha to the C=S and nitrogen atoms in thioamides are more acidic than those in ordinary amides. Theoretical studies further disclose their features. \u003c\/p\u003e\n\n\u003cp\u003eThioamides are also used as ligands to a wide variety of metals. Their unique photophysical properties and catalytic activities are described here. Characteristic features of biologicallyrelevant thioamides, e.g., thiopeptides and related compounds, are the final focus of the book. \u003c\/p\u003e\n\u003c\/div\u003e \u003ch3\u003eDetails\u003c\/h3\u003e \u003cp\u003ePublished by: Springer\u003c\/p\u003e \u003cp\u003ePublication Date: 2020-08-14\u003c\/p\u003e \u003cp\u003eFormat: Paperback\u003c\/p\u003e \u003cp\u003eISBN-13: 9789811378300\u003c\/p\u003e \u003cp\u003eDOI: 10.1007\/978-981-13-7828-7\u003c\/p\u003e \u003cp\u003eDimensions: 235cm x155cm\u003c\/p\u003e \u003cp\u003ePages: 238\u003c\/p\u003e ","brand":"Springer Nature Singapore","offers":[{"title":"Default Title","offer_id":47526768148620,"sku":"9789811378300","price":98.99,"currency_code":"USD","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0710\/9545\/1788\/files\/9789811378300.jpg?v=1776037195","url":"https:\/\/lateknightbooks.com\/products\/9789811378300","provider":"Late Knight Books and Services, LLC","version":"1.0","type":"link"}