{"product_id":"9789819615933","title":"Springer Theses","description":"\u003ch1\u003eSpringer Theses\u003c\/h1\u003e \u003ch2\u003eHarimoto, Takashi\u003c\/h2\u003e \u003cp\u003e\u003c\/p\u003e\u003cp\u003eThis book focuses on the construction of redox systems composed of doubly fused \u003cem\u003epara\u003c\/em\u003e-quinodimethane (\u003cem\u003ep\u003c\/em\u003e-QD) units and on the elucidation of the unique redox behavior. \u003cem\u003ep\u003c\/em\u003e-QD is a class of non-aromatic π-conjugated compounds that is well-known to be interconvertible scaffolds in many response systems due to its contribution of resonance structure with a planar aromatic sextet ring. This book describes studies on a strategy for precisely controlling the frontier orbital levels of \u003cem\u003ep\u003c\/em\u003e-QD-based redox systems and a nature of cationic states of π-electron systems with doubly fused \u003cem\u003ep\u003c\/em\u003e-QD units. The author revealed that multi-redox unimolecular systems with cross-linking of the two sterically strained \u003cem\u003ep\u003c\/em\u003e-QD units exhibit unique hysteretic character or have a domino effect upon electron transfer, which cannot be achieved in a monomeric \u003cem\u003ep\u003c\/em\u003e-QD-based system. Thus, these studies are milestones in creating functional redox systems unprecedented dynamic redox (\u003cem\u003edyrex\u003c\/em\u003e) behaviors. A study on cationic states of π-electron systems with doubly fused \u003cem\u003ep\u003c\/em\u003e-QD units and their intrinsic redox properties will lead to the development of unprecedented \u003cem\u003edyrex \u003c\/em\u003esystems, the frontier orbital levels of which can be precisely controlled by input of external stimuli such as electric potential and heat. This book benefits chemists with a deeper understanding of the redox-active molecules.\u003c\/p\u003e \u003ch3\u003eDetails\u003c\/h3\u003e \u003cp\u003ePublished by: Springer\u003c\/p\u003e \u003cp\u003ePublication Date: 2026-02-07\u003c\/p\u003e \u003cp\u003eFormat: Paperback\u003c\/p\u003e \u003cp\u003eISBN-13: 9789819615933\u003c\/p\u003e \u003cp\u003eDOI: 10.1007\/978-981-96-1591-9\u003c\/p\u003e \u003cp\u003eDimensions: 235cm x155cm\u003c\/p\u003e \u003cp\u003ePages: 148\u003c\/p\u003e ","brand":"Springer Nature Singapore","offers":[{"title":"Default Title","offer_id":50149005164684,"sku":"9789819615933","price":224.99,"currency_code":"USD","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0710\/9545\/1788\/files\/9789819615933.jpg?v=1779569344","url":"https:\/\/lateknightbooks.com\/products\/9789819615933","provider":"Late Knight Books and Services, LLC","version":"1.0","type":"link"}